| Titel | chair | place |
|---|---|---|
| The Role of the Metal-Ion Charge in Mineral Interface Doping | Konoplev-Esgenburg, R. / Koenig, M. / Welle, A. / Bogner, A. / Longo, R.C. / Thissen, P. (2025) |
ACS Appl. Mater. Interfaces, 2025, 17, 51395−51406 |
| Deep Learning Based Surface Classification of Functionalized Polymer Coatings | Vaez, S; Shahbazi, D; Koenig, M ; Franzreb, M; Lahann, J |
LANGMUIR 2024, DOI: 10.1021/acs.langmuir.4c03971 |
Publications 2025 / Chemistry of oxydic and organic Interfaces (COOI) + Robot-assisted and Information-based Material Synthesis (RIMS)
| Titel | chair | place |
|---|---|---|
| Correction: Inverse link prediction with graph convolutional networks for knowledge-preserving sparsification in cheminformatics | Bangian Tabrizi, E. / Jalali, M. / Houshmand, M. (2025) |
Journal of Big Data, 2025, 12, 203 |
| Multi-emission metal–organic framework (MOF)-based composites: A comprehensive review of synthesis strategies and luminescence applications | Taghavi-Kahagh, A. / Behboodi-Sadabad, F. / Salami-Kalajahi, M. (2025) |
Journal of Industrial and Engineering Chemistry, 2025, Available online 13 July 2025, in press |
| Application of Neural Networks for Advanced Ir Spectroscopy Characterization of Ceria Catalysts Surfaces | Jalali, M. / Caulfield, L. / Sauter, E. / Nefedov, A. / Yang, C. / Wöll, C. (2025) |
Advanced Intelligent Discovery, 2025; 0:e2500046, doi.org/10.1002/aidi.202500046 |
| Stabilization of Ce3+ cations via U–Ce charge transfer in mixed oxides: consequences on the thermochemical water splitting to hydrogen | Morales, C. / Tschammer, R. / Gouder, T. / Choi, Y. M. / Anjum, D. / Baunthiyal, A. / Krisponeit, J.-O. / Falta, J. / Flege, J. I. / Idriss, H. (2025) |
J. Phys. Energy, 2025, 7, 2, 025012DOI 10.1088/2515-7655/adbad9 |
| Temperature programmed desorption study of pre-irradiated TiO2 anatase in the presence of ethanol. Effect of conduction band electrons on reaction selectivity | Nadeem, M. A. / Idriss, H. (2025) |
Chemical Physics Letters, 2025, 866, 141965 |
| Changes in the Relative Acidities of Organic Compounds upon Surface Interaction: A Computational Study on the Rutile TiO2(110) Surface | Rohmann, C. / Idriss, H. / Barteau, M.A. (2025) |
J. Phys. Chem. C, 2025, 129, 8, 4059–4066 |
| Ru-based catalysts for proton exchange membrane water electrolysers: The need to look beyond just another catalyst | Sharma, S. K. / Wu, C. / Malone, N. / Titheridge, L. J. / Zhao, C. / Gupta, P. / Idriss, H. / Kennedy, J. V. / Jovic, V. / Marshall, A. T. (2025) |
International Journal of Hydrogen Energy, 2025, 102, 1461-1479 |
| Tracking the Redox Properties of CeO2 Powders by Infrared Spectroscopy: Monitoring the Defect States by O2 Adsorption and the Ce3+ Spin–Orbit Transition | Caulfield, L. / Sauter, E. / Idriss, H. / Wöll, C. (2025) |
J. Phys. Chem. C, 2025, 129, 2, 1228–1233 |
| Exploring molecule–surface interactions of urania via IR spectroscopy and density functional theory | Idriss, H. / Barral, M. A. / Di Napoli, S.M. / Murgida, G.E. / Sauter, E. / Llois, A.M. / Ganduglia-Pirovano, V. / Vildosola, V.L. / Wöll, C. (2025) |
Phys. Chem. Chem. Phys., 2025,27, 2405-2417 |
| Surface reactions of ethanol on UO2 thin film. Dehydrogenation and dehydration pathways | Idriss, H. / Gouder, T. (2025) |
Applied Surface Science, 2025, 683, Part A, 161716 |
| Titel | place | short description | |
|---|---|---|---|
| KIT. Ort der Zukunft. Seit 1825 // Die Interviews - Ute Schepers | Audio & Video KIT, KITopen-ID: 1000183856 |
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| Photoswitchable Fluorescence of Peptide-Based Hemipiperazines Inside of Living Cells | American Chemical Society (ACS), 2025, 147, 30, 26652–26662 |
Abstract Photoswitchable fluorophores that can be toggled with visible light are extremely useful for applications in super-resolution imaging. However, most small-molecule photoswitches suffer from poor aqueous solubility and limited biocompatibility and require UV-light activation. Here, we report a novel class of biocompatible, visible-light-responsive fluorophores based on hemipiperazine (HPI) scaffolds with annulated π-systems─indolo-hemipiperazines (IndHPIs) and pyrrolo-hemipiperazines (PyrHPIs). These compounds display large Stokes shifts (up to 135 nm), reversible photoisomerization with up to 620 nm wavelength of light, and, in particular examples, enhanced fluorescence quantum yields and switching thereof, augmented by internal H-bonding. Selected compounds demonstrated excellent thermal stability of their E-isomers, with half-lives of up to ∼13,000 h at 50 °C, and high fatigue resistance under repeated switching cycles. Notably, certain IndHPIs are efficiently internalized by living cells and exhibit a reversible modulation of fluorescence upon irradiation. Further mechanistic studies revealed that in vitro regeneration of the brighter isomer is mediated by glutathione (GSH) likely via a nucleophile-assisted isomerization pathway, providing a possible insight into the cellular behavior of these switches. The exceptional photophysical properties of IndHPIs position them as promising candidates for photoswitchable compounds for application in biological sciences and components of next-generation optical materials.
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| „Ziel ist das Ende von Tierversuchen im nächsten Jahrzehnt“ – Am KIT wurde ein 3R-Zentrum zur Minimierung von Tierversuchen ins Leben gerufen - Campus-Report am 11.03.2025 | Audio & Video, 2025, KITopen-ID: 1000179984 |
