A Hexakis Terpyridine-Fullerene Ligand in Six-Fold Ruthenium, Iridium, and Iron Complexes: Synthesis and Electrochemical Properties
Yan, W./ Réthoré, C. / Menning, S. / Brenner-Weiß, G. / Muller, T. / Pierrat, P. / Bräse, S. (2016)
Chemistry - A European Journal, (2016), 22 , 33, DOI:10.10020/chem.201600796
- Date: Juni 2016
An unprecedented straightforward route to six-fold terpyridine ligands around C60 , the latter being regioselectively functionalized in pseudo-octahedral positions using a six-fold Bingel reaction, is reported. Ruthenium, iridium, and iron complexes have been synthesized, and unambiguously characterized by NMR, MS, and cyclic voltammetry.