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Dr. Lars Heinke

Priv.-Doz. Dr. Lars Heinke

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Photoswitchable adsorption in metal-organic frameworks based on polar guest- host interactions

Photoswitchable adsorption in metal-organic frameworks based on polar guest- host interactions
chair:

Wang, Z. / Grosjean, S. / Bräse, S. / Heinke, L. (2015)

place:

ChemPhysChem, 16 (2015), 3779-3783, DOI:10.1002/cphc.201500829

Date: Oktober 2015

Abstract

Reversible remote-controlled switching of the properties of nanoporous metal–organic frameworks (MOFs) is enabled by incorporating photoswitchable azobenzene. The interaction of the host material with different guest molecules, which is crucial for all applications, is precisely studied using thin MOF films of the type Cu2(BDC)2(AzoBipyB). A molecule-specific effect of the photoswitching, based on dipole–dipole interactions, is found.

 

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