Application of photothermal deflection spectroscopy for the determination of iron (II) with ferrozine with sorption preconcentration on silufol. Photothermal and Photoacoutic Phenomena

  • Autor:

    Khrycheva, A.D. / Nedosekin, D.A. / Proskurnin, M.A. / Kononets, M.Y. / Pakhomova, S.V. / Faubel, W. / Heissler, S. (2008)
  • Quelle:  Eur. Phys. Special Topics (2008), 41- 44

  • Datum: 2008

  • Khrycheva, A.D. / Nedosekin, D.A. / Proskurnin, M.A. / Kononets, M.Y. / Pakhomova, S.V. / Faubel, W. / Heissler, S. (2008): „Application of photothermal deflection spectroscopy for the determination of iron (II) with ferrozine with sorption preconcentration on silufol. Photothermal and Photoacoutic Phenomena “. In: Eur. Phys. Special Topics (2008), 41- 44

Abstract

Photothermal deflection spectroscopy was applied for selective detection of the intensely coloured iron(II) chelate with ferrozine on Silufol plates. The linearity range was 1×10-11 - 6×10-8 mol cm-2 of chelate at the plate surface, which corresponded to 1×10-9 - 4×10-6 M of chelate in solution. The limits of detection and quantification are 8×10-12 and 20×10-12 mol cm-2 at the plate from 15 μL of test solution (0.5 nM and 1.5 nM in solution, respectively), which corresponded to n ×10-18 mol absolute amounts of the chelate at the detection zone.


 

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